AHP-FUZZY综合评价法在确定清洁生产审核重点中的应用研究——以武汉市某电源公司为例

清洁生产审核是将清洁生产理念转变为企业层次上操作的具体程序,在进行审核时首要步骤是确定审核重点。现阶段确定审核重点主要运用权重总和计分排序法,该方法易受审核者主观影响,审核质量不易控制。AHP-Fuzzy综合评价法作为一种系统分析方法很好地弥补了权重总和计分排序法的不足,在系统工程的很多领域都有广泛应用。通过确定银泰电源公司清洁生产审核重点,建立七工段层次模型:确立目标,明确问题;建立系统的层次结构;构造判断矩阵;进行层次的单排序及一致性检验;进行层次总排序一致性检验;根据排序结果,提出决策建议,验证了该综合评价法在清洁生产审核应用中的科学性、可行性和准确性,能将比较复杂、不够确定的多因素问题转化为有数字依据的简单易行的评价模式,为企业清洁生产的定量考核和指标化管理提供了一个科学的评价方法。     

环境影响评价基础数据库标准规范体系研究

环境影响评价基础数据库是对环境影响评价的重要资源信息支撑,其自身的标准化水平直接关系到环境影响评价基础数据的持续积累、开发利用和共享服务,当前迫切需要建立其标准规范体系。本文分析了环境影响评价基础数据库标准规范在环境标准中的定位和业务需求,基于对国内外相关资源信息标准体系对比分析,提出了包括三类标准的体系结构,即指导标准、通用标准和专用标准。借鉴开放地理空间联盟(OGC)参考模型的企业视角,设计了环境影响评价基础数据库标准规范体系框架,具体包括4项指导标准、涵盖6类标准子项的30项通用标准和若干专用标准。基于已有实践经验,提出了标准规范制定的4条基本原则。     

江安河武侯区段水质改善的环境经济效益研究

根据成都市江安河武侯区段2010年11月-2011年3月的水质监测数据,结合中国地表水环境质量标准(GB3838-2002)和四川省实际确定水体中各污染物因子的本底浓度对该区段污水处理环境效益进行了分析。首先通过污染经济损失模型计算COD、BOD5、NH3-N、TP、SS和硫化物对水经济价值的损失率,然后在讨论COD、NH3-N、TP和硫化物减排情况的基础上计算了各种污染指标减排至达标后所产生的环境经济效益。研究结果表明,江安河武侯区段水体污染的综合污染损失率高达99.99%,如果各种污染物减排达标至IV类标准产生的环境经济效益14 912万元人民币/a,而减排达标至III类标准产生的环境经济效益更是高达15 786万元人民币/a。     

Joint effects of Penta-BDE and heavy metals on Daphnia magna survival, its antioxidant enzyme activities and lipid peroxidation

The joint toxicity of Penta-BDE (Pe-BDE) and heavy metals including cadmium and copper on Daphnia magna (D. magna) was evaluated on the basis of determining the 48 h survival, antioxidative enzyme responses, and lipid peroxidation. The response was classified as additive, greater than additive, or less than additive by comparing the measured “toxic units, TU” with one. Based on the survival of D. magna, less-than-additive interactions were found in most of mixtures treatments. This may be attributed to the different toxicity mechanism between Pe-BDE and metals. Cu and Cd played a greater role in toxicity than what Pe-BDE did. As for the superoxide dismutase (SOD) and catalase (CAT) activity, most response was less than additive. For the glutathione S-transferases (GST) activity, most of the greater-thanadditive responses were found in the Cu plus Pe-BDE treatments, but the additive responses occurred in Cd plus Pe-BDE treatments and binary metal treatments. For lipid peroxide levels, which were measured as malondialdehyde (MDA) levels, less-than-additive response occurred in the 50% Cd plus 50% Cu and ternary mixture treatments. Results suggested that Pe-BDE, Cd, and Cu could induce different patterns of antioxidant enzyme responses, such as antioxidant/prooxidant responses, depending on their capability to produce reactive oxygen species and antioxidant enzymes to detoxify them.     

Adsorption of humic acid from aqueous solution on bilayer hexadecyltrimethyl ammonium bromide-modified zeolite

Surfactant-modified natural zeolites (SMNZ) with different coverage types were prepared by loading hexadecyltrimethyl ammonium bromide (HTAB) onto the surface of a natural zeolite. The adsorption behavior of humic acid (HA) on SMNZ was investigated. Results indicate that the adsorbent SMNZ exhibited a higher affinity toward HA than the natural zeolite. HA removal efficiency by SMNZ increased with HTAB loading. Coexisting Ca²⁺ in solution favored HA adsorption onto SMNZ. Adsorption capacity decreased with an increasing solution pH. For typical SMNZ with bilayer HTAB coverage, HA adsorption process is well described by a pseudo-second-order kinetic model. The experimental isotherm data fitted well with the Langmuir model. Calculated maximum HA adsorption capacities for SMNZ with bilayer HTAB coverage at pH 5.5 and 7.5 were 63 and 41 mg·g⁻¹, respectively. E2/E3 (absorbance at 250 nm to that at 365 nm) and E4/E6 (absorbance at 465 nm to that at 665 nm) ratios of the residual HA in solution were lower than that of the original HA solution. This indicates that the HA fractions with high polar functional groups, low molecular weight (MW), and aromaticity had a stronger tendency for adsorption onto SMNZ with bilayer HTAB coverage. Results show that HTAB-modified natural zeolite is a promising adsorbent for removal of HA from aqueous solution.     

Microwave enhanced stabilization of copper in artificially contaminated soil

Microwave processing was used to stabilize copper ions in soil samples. Its effects on the stabilization efficiency were studied as a function of additive, microwave power, process time, and reaction atmosphere. The stabilization efficiency of the microwave process was evaluated based on the results of the toxicity characteristic leaching procedure (TCLP) test. The results showed that the optimal experimental condition contained a 700W microwave power, 20 min process time and 3 iron wires as the additive, and that the highest stabilization efficiency level was more than 70%. In addition, the different reaction atmospheres showed no apparent effect on the stabilization efficiency of copper in the artificially contaminated soil. According to the result of the Tessier sequential extraction, the partial species of copper in the contaminated soil was deduced to transform from unstable species to stable states after the microwave process.     

包埋固定化微生物处理含氮废水的研究进展

氮污染日益严重,含氮废水处理越来越受到重视。传统生物脱氮技术存在着很多问题,微生物固定化技术可以弥补传统生物脱氮方法中的不足之处,达到高效脱氮的目的。包埋固定法是应用最广泛的一种微生物固定方法,也是国内外研究的热点之一。主要介绍了包埋固定化技术原理和常用的固定化载体,以及国内外学者对包埋固定化技术生物脱氮的研究进展情况,并针对该技术实用化提出了需要解决的问题。     

影响总磷的显色实验细节探讨

针对环境样品采用钼酸铵分光光度法测定的总磷中,影响显色的二个因素进行了分析,对加入显色刺后的混合过程对显色结果的影响,以及环境条件的温度对显色的影响进行了研究,对总磷测定时准确度及精密度的提高有着重要的参考价值,是对钼酸铵法测定总磷方法的完善。     

高径比对猪场废水脱氮与沼气脱硫耦联反应器的影响

采用填料鼓泡塔反应器研究其高径比对猪场废水脱氮与沼气脱硫耦联过程的影响,比较了3种不同高径比(8∶1、3∶1、2∶1)反应器的废水脱氮与沼气脱硫效能.在温度30～32℃、空塔停留时间6.70 min、水力停留时间3.35 d、沼气中H2 S浓度1 414～1 838 mg.m-3、进水NO x--N浓度114～243 mg.L-1的条件下,高径比2∶1反应器的运行较稳定,且处理效果较好,硫化氢去除率平均值为96.7%,NO x--N去除率平均值达到88.7%;而高径比8∶1和3∶1反应器的运行不太稳定,硫化氢去除率的平均值分别为68.0%、80.4%,NO x--N的去除率平均值分别为89.7%、90.2%.主要是因为高径比2∶1反应器的实际气速(3.12×10-2 m.s-1)比高径比3∶1、8∶1反应器的实际气速(分别为3.62×10-2 m.s-1和6.64×10-2 m.s-1)更慢,其气液传质系数(1.79×10-5 s-1)比高径比3∶1、8∶1反应器的气液传质系数(分别为1.64×10-5 s-1和1.55×10-5 s-1)更大,传质效果更好.处理效能试验结果以及反应器流体力学特征参数均表明,高径比2∶1反应器为最适合的反应器.     

Source attributions of heavy metals in rice plant along highway in Eastern China

Air and soil pollution from traffic has been considered as a critical issue to crop production and food safety, however, few efforts have been paid on distinguish the source origin of traffic-related contaminants in rice plant along highway. Therefore, we investigated metals (Pb, Cd, Cr, Zn and Cu) concentrations and stable Pb isotope ratios in rice plants exposed and unexposed to highway traffic pollution in Eastern China in 2008. Significant differences in metals concentrations between the exposed and unexposed plants existed in leaf for Pb, Cd and Zn, in stem only for Zn, and in grain for Pb and Cd. About 46% of Pb and 41% of Cd in the grain were attributed to the foliar uptake from atmosphere, and there were no obvious contribution of atmosphere to the accumulations of Cr, Zn and Cu in grain. Except for Zn, all of the heavy metals in stem were attributed to the root uptake from soil, although significant accumulations of Pb and Cd from atmosphere existed in leaf. This indicated that different processes existed in the subsequent translocation of foliar-absorbed heavy metals between rice organs. The distinct separation of stable Pb isotope ratios among rice grain, leaf, stem, soil and vehicle exhaust further provided evidences on the different pathways of heavy metal accumulation in rice plant. These results suggested that further more attentions should be paid to the atmospheric deposition of heavy metals from traffic emission when plan crop layout for food safety along highway.